The Real Gas Equation

Natural gas departs from ideal behavior at reservoir pressure, and the z factor is the correction that keeps volumes honest.

The equation

pV = z n R T
  • z is the gas deviation factor, near 1 at low pressure
  • Dips to about 0.8 at moderate pressure, climbs above 1 when very high
  • Read from Standing Katz charts using pseudo reduced properties

Worked example

At conditions where z is 0.85, a gas occupies only 85 percent of its ideal volume. For a reservoir holding gas at 3,000 psi, using z of 1 would overstate gas in place by 18 percent, an expensive rounding error.

When to use it

Every gas material balance runs on p/z: plot it against cumulative production and a straight line points at the initial gas in place. Departures from that line whisper about water drive or compartment boundaries.

Related Calculators and Reference